Title
Sinteza, karakterizacija i potencijalna citotoksičnost O,O'-dialkil-(S,S)-etilendiamin-N,N'-DI-2-(4-metil)-pentanoati i odgovarajućih paladijum(II), platina(II) i platina (IV) kompleksa
Creator
Vujić, Jelena M., 1983-
Copyright date
2012
Object Links
Select license
Autorstvo-Nekomercijalno-Bez prerade 3.0 Srbija (CC BY-NC-ND 3.0)
License description
Dozvoljavate samo preuzimanje i distribuciju dela, ako/dok se pravilno naznačava ime autora, bez ikakvih promena dela i bez prava komercijalnog korišćenja dela. Ova licenca je najstroža CC licenca. Osnovni opis Licence: http://creativecommons.org/licenses/by-nc-nd/3.0/rs/deed.sr_LATN. Sadržaj ugovora u celini: http://creativecommons.org/licenses/by-nc-nd/3.0/rs/legalcode.sr-Latn
Language
Serbian
Cobiss-ID
Theses Type
Doktorska disertacija
Other responsibilities
mentor
Trifunović, Srećko R., 1954-
član komisije
Kaluđerović, Goran N.
član komisije
Sabo, Tibor J., 1958-
član komisije
Arsenijević, Nebojša, 1958-
član komisije
Petrović, Biljana V., 1970-
Academic Expertise
Prirodno-matematičke nauke
University
Univerzitet u Kragujevcu
Faculty
Prirodno-matematički fakultet
Group
Katedra Instituta za hemiju
Alternative title
Synthesis, characterizaon and potenal cytotoxity of o,o'-dialkil-(s,s)-ethilenediamine-n,n'- di--2-(4-methyl)-pentanoate and the corresponding palladium(ii), planum(ii) and planum(iv) complexes
Publisher
Крагујевац : [Ј. М. Вујић],
Format
PDF/A (listova)
description
datum odbrane 14.09.2012.
Прилози.
Умножено за одбрану.
ПРИРОДНО-МАТЕМАТИЧКИ ФАКУЛТЕТ, Универзитет у Крагујевцу., 2012, др хемијских наука.
Извод ; Summary.
Библиографија: листови 101-107.
Abstract (en)
This works describes synthesis, characterization and potential cytotoxity of O,O'-
-dialkyl-(S,S)-ethylenediamine-N,N'-di-2-(4-methyl)-pentanoic acid, [(S,S)-H4eddl]Cl2, as well as their corresponding palladium(II), platinum(II) and platinum(IV) complexes. Esters (S,S)-R2eddl·2HCl (R = ethyl, n-propyl, n-butyl and n-pentyl) were obtained by instillation of thionyl chloride in an appropriate absolute alcohol, and then refluxing with addition of (S,S)-ethylenediamine-N,N'-di-2-(4-methyl)-pentanoic acid. All of the esters were obtained as dihydrochlorides: (S,S)-Et2eddl·2HCl, (S,S)-Pr2eddl·2HCl, (S,S)-Bu2eddl·2HCl,
(S,S)-Pe2eddl·2HCl. Esters were characterized by elemental analysis, IR and NMR
spectroscopy, and in the case of (S,S)-Pr2eddl·2HCl the structure was confirmed by X-ray structural analysis.
Authors Key words
Paladijum(II) kompleksi
Authors Key words
Platina(II) kompleksi, Palatina(IV) kompleksi
Classification
54
Type
monograph
manuscript text - theses
Text
Abstract (en)
This works describes synthesis, characterization and potential cytotoxity of O,O'-
-dialkyl-(S,S)-ethylenediamine-N,N'-di-2-(4-methyl)-pentanoic acid, [(S,S)-H4eddl]Cl2, as well as their corresponding palladium(II), platinum(II) and platinum(IV) complexes. Esters (S,S)-R2eddl·2HCl (R = ethyl, n-propyl, n-butyl and n-pentyl) were obtained by instillation of thionyl chloride in an appropriate absolute alcohol, and then refluxing with addition of (S,S)-ethylenediamine-N,N'-di-2-(4-methyl)-pentanoic acid. All of the esters were obtained as dihydrochlorides: (S,S)-Et2eddl·2HCl, (S,S)-Pr2eddl·2HCl, (S,S)-Bu2eddl·2HCl,
(S,S)-Pe2eddl·2HCl. Esters were characterized by elemental analysis, IR and NMR
spectroscopy, and in the case of (S,S)-Pr2eddl·2HCl the structure was confirmed by X-ray structural analysis.
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